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Stand with your feet placed shoulder width apart and arms extend straight to your sides, raised at shoulder height. Now, do 50 small circles with your hands by rotating them in the forward direction. Then switch to 50 small backward circles. The backward and forward arm movement tones all the muscles of the arms including the triceps, biceps, shoulders and back muscles as well.
What you can do is remove body fat from your entire body. Basically, you have to decrease your overall body fat composition if you want to lose weight from any specific place on your body. When you do that, you are going to eventually target the part of your body you want and you're going to lose body fat there. You can't just do 1000 push-ups every day and lose arm fat. Instead, you have to lose body fat in your entire body while building those arm muscles. You build up those muscles so that when your body fat percentage is low enough, they can show through.
Get down on all fours with your knees placed directly below your hips and palms placed directly below your shoulders. Now, raise your right arm forward and stretch your left leg backward at the same time. Create a tension in your back by flexing your foot. Hold the position for a few seconds and then come back to the starting position. Repeat the same using your left arm and right leg. Repeat 15 to 20 times on both sides.